Msds contains all of the information required by those regulations. Material safety data sheet pharmaceutical chemistry. Epas toxics release inventory reported that in 2007, environmental releases of hydrazine from 23 facilities totaled 16,759 lb, 14,570 lb. Its residue in food and tobacco is highly toxic, causing cns disturbances and liver damage. Hydrazine undergoes dehydrogenation in the presence of bimetallic nirh nanoparticles nps supported on nitrogendoped porous carbon npc derived from metalorganic frameworks zif8 to afford hydrogen. Hydrazine is a highly reactive base and reducing agent used in many industrial and medical applications. Hydrazine and hydrazine sulfate may be released to the environment through production, use, and waste disposal atsdr 1997, hsdb 2009. After neutralization, transfer material to appropriate dot container for proper disposal.
Revised on 05292015 page 5 of 6 carcinogenicity iarc 1 group 1. Hydrazine sulfate is soluble in water but practically insoluble in ethanol. Firstaid measures general advice show this safety data sheet to the doctor in attendance. Hazardous decomposition products potassium oxides, chromium oxides. Anhydrous hydrazine ah monomethyl hydrazine mmh uns dimethyl hydrazine udmh hydrogen peroxideh 2 o 2 dinitrogen tetroxiden 2 o 4 hydroxylterminated polybutadienehtpb ammonium perchlorate ap e thylamine 1anhydrous hydrazine.
Chemtrec 8004249300 outside usa 7035273887 1216 6th ave n kent wa 98032 phone. Firstaid measures eye contact irritation irrigate eyes with water immediately for at least 15 minutes. Chemical product and company identification product name. Hydrazine and hydrazine sulfate national toxicology program. Phenyl hydrazine cas no 100630 material safety data sheet sds msds. Potassium dichromate, crystal, acs columbus chemical. Skin potential significant contribution to overall exposure by the cutaneous r oute. General statement hydrazine hydrate is a colourless liquid highly soluble in water. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Hydrazine hydrate 100% 64% hydrazine hydrazine hydrate 55% 35% hydrazine chemical name.
As a waterbased solution, hydrazine hydrate and its derivatives are supplied by arkema to be widely used as reducing agent, blowing agent, corrosion inhibitor, oxygen scavenger or intermediate of synthesis our product found applications in various industrial sectors such as water treatment, polymerization, agrochemicals, and pharmaceuticals. Hydrazine sulfate salt is a potential anticachexia agent for treating cancer patients. Hydrazine sulphate cas no 10034932 material safety data sheet sds msds. In biological applications, hydrazine and its derivatives exhibit antidepressant properties by inhibiting monoamine oxidase mao, an enzyme that catalyzes the deamination and inactivation of certain stimulatory neurotransmitters such as norepinephrine and dopamine. Hydrazine is highly toxic and dangerously unstable unless handled in solution as e. Hazardous decomposition products oxygen, oxides of potassium, chromium dioxide, toxic chromium oxide fumes. Onheatinginaflameitmelts,andformsagasratherexplosively, partof the sulfuricacidbeingreduced tosulfur. Material safety data sheet hydrazine sulphate msds section 1. Central drug house p ltd 728 vardaan house new delhi2 india. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Hydrazine hydrate, 80% hydrazine, 51% revision date 11jul2019 4. Hydrazine is the simplest diamine 6 mainly used as a reducing agent.
The information provided in this safety data sheet sds is correct to the best of our knowledge. Property hydrazine hydrazine sulfate molecular weight 32. Hydrazine hydrate, 80% hydrazine, 51% revision date 11jul2019 nfpa 6. This material does not contain any class 1 ozone depletors. As a waterbased solution, hydrazine hydrate and its derivatives are supplied by arkema to be widely used as reducing agent, blowing agent, corrosion inhibitor, oxygen scavenger or intermediate of synthesis. The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication. If seeking medical attention provide sds document to physician. Hydrazine is an inorganic compound with the chemical formula n2h4. Caustic potash membrane dilute solution 45%, 48%, 50%.
Product and company identification product identifier. Classes of incompatible chemicals should be segregated from each other during storage, according to hazard class. It is a simple pnictogen hydride, and is a colorless and flammable liquid with an ammonialike odor. Hydrazine sulphate material safety data sheet cas no. In the case of contact with eyes, rinse immediately with plenty of water and seek medical. Reacts explosively with potassium and sodium dichromate mellor 11. Chemtrec 8004249300 outside usa 7035273887 1216 6th ave n. Science company safety data sheet 2016 rv5 page 2 of 5 printed 1112017 section 4. Hydrazine is the simplest diamine mainly used as a reducing agent. Dilute hydrazine hydrate with water so the concentration of hydrazine is less than 5% ww. Aqueous hydrazine solution diamide hydrate cas number. Explodes on contact with dicyanofurazan, nhalomides, potassium, silver compounds, sodium hydroxide. For the full text of the rphrases mentioned in this section, see section 16. Incompatible materials organic materials, powdered metals, hydrazine.
Arkema thiochemicals hydrazine hydrate gps 20141031 v0 substance name. Hydrazine hydrate 80% extra pure msds cas 10217524 msds. This msds has been prepared according to the hazard criteria of the controlled products regulations cpr and the msds contains all of the information required by the cpr. Potassium dichromate 98 7778509 2319066 k 2 cr 2 o 7 294. Dry powders can build static electricity charges when subjected to the friction of transfer and mixing operations. Add an equal volume of 5% calcium hypochlorite aqueous solution. During the measurement of the shock sensitivity of a mixture containing hydrazine, a drop of the mixture fell on a tetryl explosive. Hydrazine sulphate material safety data sheet cas no 1003493. Pdf aqueous hydrazine as a promising candidate for. Not listed by acgih, iarc, niosh, ntp, or osha teratogenicity.
Hydrazine hydrate, hydrazine hydroxide, hydrazinium hydroxide. Reducing agents, acids, strong bases, acetic anhydride, hydrazine. Skin contact irritation wash affected area with water. The substance is marketed as hydrate form and is covered by the registration of the anhydrous. Physical and chemical properties of hydrazine and hydrazine sulfate are listed in the following table. The tetryl immediately burst into flames asesb 105. Reported to cause birth defects in rats exposed to 20,000 ppm. Reducing agents, acids, strong bases, acetic anhydride, hydrazine, hydroxylamine, nitric acid, oils, hydrochloric acid. Ac19670, ac196710050, ac19671, ac196715000 synonyms. Hydralazine apresoline is a medication prescribed to treat hypertensive crisis, congestive heart failure, and high blood pressure alone or in combination with other high blood pressure medications. Potassium dichromate 56 7778509 2319066 k 2 cr 2 o 7. Material safety data sheet hydrazine hydrate 80% extra pure msds cas. This material does not contain any hazardous air pollutants. Accidental release measures personal precautions ensure adequate ventilation.
Ac411745000, ac611195000, bp1200100, o3106500 synonyms. Safety data sheet northwest missouri state university. Hydrazine is an inorganic compound with the chemical formula n 2 h 4. Material safety data sheet potassium phosphate, monobasic. Hydrazine sulphate material safety data sheet cas no 10034. Chemical product and company identification section 1. Phenyl hydrazine material safety data sheet cas no 100630. Specific treatment see supplemental first aid instructions on this label if eye irritation persists get medical adviceattention. Ignites spontaneously if mixed with nitrous oxide mellor 8, supp. Potassium hydroxide safety data sheet according to federal register vol.
Potassium dichromate ld50 skin, rabbit 14 mgkg ld50 oral, rat 25 mgkg ldlo oral, child 26 mgkg potassium dichromate is listed as a carcinogen by osha, by the ntp as known human carcinogen as chromium hexavalent compounds and by the iarc as group 1, known human carcinogen as chromium vi compounds. Hydrazine, which is the simplest diamine, was investigated for its viability as a sorbent for carbon dioxide co2 capture from flue gas using lab scale experiments. Fisher scientific 1 reagent lane fair lawn, nj 07410 for information, call. Safety data sheet according to 29cfr19101200 and ghs rev. Hydrazine hydrate is a clear and colorless liquid at ambient. Hydrazine anhydrous,monomethyl hydrazinemmh,unsdimethyl. Disclaimer the information presented in this material safety data sheet msds sds. Read the product manufacturers material safety data. It is a simple pnictogen hydride, and is a colorless and flammable liquid with an ammonialike odor hydrazine is highly toxic and dangerously unstable unless handled in solution as e. Canadian ingredient disclosure list section 16 additional information msds creation date. As of 2015, the world hydrazine hydrate market amounted.
Hydrazine sulfate salt may be used in the synthesis of symmetrically 3,5disubstituted 4amino1,2,4triazoles, poly 1,3,4oxadiazole copolymers and salicylaldazine. Phenyl hydrazine material safety data sheet cas no. Identification of the substancemixture and of the companyundertaking. Neutralize spilled hydrazine by diluting with water to a 5% or less solution. Laboratory chemical identification of manufacturer. Sigmaaldrich 3050 spruce street saint louis mo 63103 usa telephone.
Sigmaaldrich offers a number of hydrazine monohydrate products. Koh, liquid potash, potassium hydroxide product use. Potassium hydroxide, 20% wv safety data sheet according to federal register vol. Our product found applications in various industrial sectors such as water treatment, polymerization, agrochemicals, and pharmaceuticals. The neutral saltor monacid salt is formedwhenhydrazinehydrate is. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Identification of the substancemixture and of the companyundertaking 1. Incompatibility of common laboratory chemicals when certain hazardous chemicals are stored or mixed together, violent reactions may occur because the chemicals are unsuitable for mixing, or are incompatible.
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